Spatial measurements of stream baseflow,a relevant method for aquifer characterization and permeability evaluation. Application to a hard‐rock aquifer,the Oman ophiolite

The structure, functioning and hydrodynamic properties of aquifers can be determined from an analysis of the spatial variability of baseflow in the streams with which they are associated. Such analyses are based on simple low‐cost measurements. Through interpreting the hydrological profiles (Q = f(A)) it is possible to locate the aquifer(s) linked to the stream network and to determine the type of interrelated flow, i.e. whether the stream drains or feeds the aquifer. Using an analytical solution developed for situations with a positive linear relationship, i.e. where the baseflow increases linearly with increasing catchment size, it is also possible to estimate the permeability of the aquifer(s) concerned at catchment scale. Applied to the hard‐rock aquifers of the Oman ophiolite, this method shows that the ‘gabbro’ aquifer is more permeable than the ‘peridotite’ aquifer. As a consequence the streams drain the peridotites and ‘leak’ into the gabbro. The hydrological profiles within the peridotite are linear and positive, and indicate homogeneity in the hydrodynamic properties of these formations at the kilometre scale. The permeability of the peridotite is estimated at 5 · 10^?7 to 5 · 10^?8 m/s. Copyright © 2004 John Wiley & Sons, Ltd.     

Deciphering polymetamorphic episodes in high-grade metamorphic orogens: Constraints from PbSL, Sm/Nd and Lu/Hf garnet dating of low- to high-grade metasedimentary rocks from the Kaoko belt (Namibia)

Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation.     

Controls on porphyroblast size along a regional metamorphic field gradient

Garnet-bearing schists from the Waterville Formation of south-central Maine provide an opportunity to examine the factors governing porphyroblast size over a range of metamorphic grade. Three-dimensional sizes and locations for all garnet porphyroblasts were determined for three samples along the metamorphic field gradient spanning lowest garnet through sillimanite grade, using high-resolution X-ray computed tomography. Comparison of crystal size distributions to previous data sets obtained by stereological methods for the same samples reveals significant differences in mode, mean, and shape of the distributions. Quantitative textural analysis shows that the garnets in each rock crystallized in a diffusion-controlled nucleation and growth regime. In contrast to the typical observation of a correlation between porphyroblast size and position along a metamorphic field gradient, porphyroblast size of the lowest-grade specimen is intermediate between the high- and middle-grade specimens’ sizes. Mean porphyroblast size does not correlate with peak temperatures from garnet-biotite Fe-Mg exchange thermometry, nor is post-crystallization annealing (Ostwald Ripening) required to produce the observed textures, as was previously proposed for these rocks. Robust pseudosection calculations fail to reproduce the observed garnet core compositions for two specimens, suggesting that these calc-pelites experienced metasomatism. For each of these two specimens, Monte Carlo calculations suggest potential pre-metasomatism bulk compositions that replicate garnet core compositions. Pseudosection analyses allow the estimation of the critical temperatures for garnet growth: ∼481, ∼477, and ∼485°C for the lowest-garnet-zone, middle-garnet-zone, and sillimanite-zone specimens, respectively. Porphyroblast size appears to be determined in this case by a combination of the heating rate during garnet crystallization, the critical temperature for the garnet-forming reaction and the kinetics of nucleation. Numerical simulations of thermally accelerated, diffusion-controlled nucleation, and growth for the three samples closely match measured crystal size distributions. These observations and simulations suggest that previous hypotheses linking the garnet size primarily to the temperature at the onset of porphyroblast nucleation can only partially explain the observed textures. Also important in determining porphyroblast size are the heating rate and the distribution of favorable nucleation sites.     

苏北盘石山、练山地幔捕虏体的PGE地球化学

通过锍镍火试金预富集法,分析了位于郯庐断裂带东侧的盘石山、练山地幔橄榄岩包体中铂族元素(PGE)和Au含量.不同于部分熔融残留成因地幔橄榄岩中通常所观察到的负斜率型或平坦型的分布模式,这两地的地幔橄榄岩以Pt、Pd、Ru相对富集,Ir、Rh相对亏损的"燕子型"分布模式为特征.Pt、Pd等不相容元素富集说明上地幔除经历过早期的部分熔融外,还经历了后期富Pt、Pd的高熔/岩比的熔(流)体的层析分离交代作用影响.盘石山地幔橄榄岩的PGE总量比练山高,Os的含量也比原始地幔值高;而练山地幔橄榄岩的Os含量比原始地幔值低,说明交代作用带走了练山地幔橄榄岩中的Os,却没有很大改变盘石山地幔橄榄岩中的Os含量,这可能与交代熔(流)体含硫量饱和程度有关.Rh的负异常可能与部分熔融过程中熔体较低的fo2有关.     

西准噶尔克拉玛依蛇绿混杂岩中的石榴角闪岩

本文报道在准噶尔地区发现的石榴角闪岩,该岩石产在克拉玛依蛇绿混杂岩带的百口泉地区.石榴角闪岩主要由钙质角闪石、富钠斜长石和黝帘石组成,含少量钛铁矿、绿帘石、绿泥石、榍石、石榴石、普通辉石、金红石、磷灰石、钠长石、石英和锆石.石榴石中常包裹磷灰石、金红石、钛铁矿、石英和锆石.黝帘石 富钠斜长石组合中出现少量钙铝榴石残余.百口泉石榴角闪岩中石榴石的化学组成特征以及其中出现的金红石-钛铁矿-磷灰石-石英-锆石包体组合说明,该岩石不是异剥钙榴岩退变质的产物,而是榴辉岩退变的产物(辅助证据包括二辉橄榄岩中发育的辉石出溶结构和辉石塑性变形特征).百口泉石榴角闪岩至少记录了四个阶段:石榴石-单斜辉石-金红石-磷灰石-石英-锆石组成的阶段Ⅰ(可能为榴辉岩相),普通辉石-钛铁矿-磷灰石-角闪石组成的退变阶段Ⅱ,角闪石-斜长石-榍石-钛铁矿构成的阶段Ⅲ(角闪岩相),以及绿帘石-石英-绿泥石构成的绿片岩相变质阶段Ⅳ.尽管上述演化历史存在一些不确定性,石榴角闪岩的发现为深入研究西准噶尔地区古生代洋壳俯冲带的性质及其演化过程提供了新的物质基础.     

大别山地区石榴石橄榄岩的岩石学和地球化学

本文首次对我国石榴石橄榄岩类岩石进行系统的岩石学和地球化学研究。通过对大别山地区两个不同类型岩体中的石榴石橄榄岩的岩石学、岩石化学、矿物化学和稀土元素地球化学研究,表明这类岩石属钙碱性系列超基性岩;与地幔成分相比,富集易熔元素,亏损难熔元素;利用矿物地质温压计估算其形成压力为2×10~9pa,成岩温度为600～700℃具有正铕异常和轻稀土元素富集特征 推测为地壳下部的超基性岩经深成变质而成。     

石榴石橄榄岩的熔融实验及其地质意义

在20×10~9Pa和25×10~9Pa条件下,对石榴石橄榄岩进行的14次高温高压熔融实验研究表明,在1600℃时石榴石橄榄岩开始熔融(初熔),熔体中的SiO_2>70％,Na_2O+K_2O>8％,类似于A型花岗岩成分。本实验为地幔花岗岩的成因提供了证据。     

鲁苏榴辉岩套的特征及其动力学演化

鲁苏榴辉岩套以广泛分布各类榴辉岩、密切伴生石榴石橄榄岩、石榴石麻粒岩等高压岩石组合 ,普遍发育韧性变形带 ,大量出露燕山晚期碱性花岗岩及深源脉岩为特征。它已经历三迭纪早期华南陆块与华北陆块的碰撞事件、大陆逆掩推覆构造事件及后期白垩纪早期开始的大陆伸展构造事件 ,是我国华南陆块与华北陆块之间的重要过渡单元。     

南极中山站石榴石变粒岩的岩石学矿物学及其变质作用研究

本文报道了南极拉丝曼丘陵“中山站”石榴石变粒岩的岩石学和矿物化学特征;确定了其矿物组合及世代演化关系,利用电子探针分析了其特征变质矿物的化学组成,最后推断东南极拉丝曼丘陵地区曾发生过麻粒岩相变质作用和混合岩化作用。     

北大别饶拔寨石榴辉石岩P-T-t轨迹及其构造意义

P-T-t轨迹作为变质岩的重要研究方法之一，对揭示岩石的构造演化过程具有重要意义。北大别饶拔寨镁铁-超镁铁岩形成的构造环境和就位过程长期以来尚存争议。本文通过岩相学观察、矿物化学研究和温压计计算，揭示出饶拔寨石榴辉石岩经历了四个变质演化阶段：1）超高压变质阶段（M1）：主要根据石榴子石中金红石的出溶，单斜辉石中石英的出溶和磷灰石中不透明矿物的出溶，结合前人研究，认为饶拔寨石榴辉石岩经历过超高压变质阶段（≥2.5GPa）；2）高压麻粒岩相阶段（M2）：矿物组合为石榴子石（变斑晶）和单斜辉石（基质）+斜长石（基质），记录的温压条件为T=648~700℃，P=1.47~1.94GPa；3）中压麻粒岩相阶段（M3）：以石榴子石外围发育的主要由斜方辉石+斜长石组成的内圈"白眼圈"为特征，形成的温压条件为T=781~796℃，P=0.92~0.98GPa；4）角闪岩相阶段（M4）：以石榴子石变斑晶周围发育的外圈"白眼圈"为特征，其矿物组合为角闪石+斜长石的后成合晶，形成的温压条件为T=663~685℃，P=0.50~0.58GPa。石榴辉石岩的锆石SIMS U-Pb定年得到了3组不同的交点年龄，分别为208.1~202.1Ma、227.6Ma和817.7Ma。根据锆石包裹体中角闪石+斜长石的组合，推断208.1~202.1Ma代表了角闪岩相变质年龄的下限，227.6Ma则是高压麻粒岩相的下限年龄，而新元古代年龄（817.7Ma）与区域上的变质岩原岩年龄一致，可能代表了其原岩年龄。结合前人研究，饶拔寨石榴辉石岩记录了顺时针的P-T-t轨迹，揭示了板片俯冲（超高压变质）-碰撞-折返（降压升温过程，~227Ma）-抬升（降压降温过程，208~202Ma）的完整过程。